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101.
通过高分离度快速液相色谱-四极杆飞行时间质谱(RRLC-Q-TOF MS)和超高效液相色谱-三重四极杆质谱(UPLC-QQQ MS)法对原人参三醇型皂苷Re、Rg 1、Rg 2、Rh 1、Rf、F 1、R 1在人肠道菌群中的转化产物进行定性、定量分析,确定原人参三醇型皂苷的代谢产物、转化途径和60 h时的转化率。结果表明,人参皂苷Re的转化产物为人参皂苷Rg 1、Rg 2、Rh 1、F 1和PPT,转化率为91%;人参皂苷Rg 1的转化产物为人参皂苷Rh 1、F 1和PPT,转化率为80%;人参皂苷Rg 2的转化产物为人参皂苷Rh 1和PPT,转化率为73%;人参皂苷Rh 1和F 1主要通过PPT代谢,转化率分别为82%和81%;人参皂苷Rf的转化产物为人参皂苷Rh 1和PPT,转化率为89%;三七皂苷R 1的转化产物为人参皂苷Rg 1、R 2、Rh 1和PPT,转化率为79%。原人参三醇型皂苷类成分可被人肠道菌群代谢,主要通过丢失糖残基形成转化产物,而次级皂苷和苷元是人参在体内发挥药理作用的物质基础。 相似文献
102.
103.
《Journal of the European Ceramic Society》2020,40(13):4509-4516
The relationship between enhanced dielectric property and structural distortion in tungsten bronze structure ceramics was discussed in this work. The ceramics with the composition of (Ba1-xCax)2NaNb5O15 (x = 0, 0.1, 0.2, 0.3, 0.4) were fabricated via conventional solid-state method. All ceramics were pure without secondary phase and the distinct lattice distortion in structure was testified by Rietveld XRD refinement. Compared with the un-doped composition, the maximum polarization and energy storage density were strongly enhanced according to the ferroelectric property measurements, which were contributed to the distortion of NbO6 octahedron induced by the variation of ionic radius. The actually pulsed charge-discharge property of x = 0.3 ceramic was tested, whist excellent power density (PD = 35.106 MV/cm3) and discharge energy density (Wd = 0.29 J/cm3) were obtained at 100 °C under 120 kV/cm, revealing the potential for application of Ba2NaNb5O15 system-based ceramics in harsh environment. 相似文献
104.
以某型飞机中无扩口液压导管为研究对象,结合飞机液压导管实际安装以及保压工况,利用有限元软件ANSYS中多线性随动强化来模拟导管弹塑性本构模型;对处于不同安装力矩以及恒定压力下的导管连接件进行仿真分析,研究安装力矩对导管管接头处的应力应变以及密封性能的影响,并给出参考安装力矩。构建液压导管安装试验台,利用力矩扳手采集拧紧力矩值并使用液压油车对导管进行加压试验,验证不同安装力矩对导管管接头密封性能的影响。结果表明:导管与卡套之间的胀形区域产生的大变形以及应力集中是引起导管管接头渗漏的主要原因之一;所提出的密封性能仿真方法可以较为准确地模拟拧紧力矩与密封性能的关系,为实际工程中导管安装提供依据。 相似文献
105.
106.
目的 提高涂层刀具在高速工况下的切削寿命。方法 利用电弧离子镀技术在高速钢试样块和刀具表面制备不同弧电流(60、80、100 A)的AlCrBN涂层。采用扫描电镜(SEM)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)、轮廓仪、洛氏压痕仪、划痕仪、显微硬度计、球盘摩擦磨损试验仪和切削试验对涂层的微观结构和性能进行研究分析。结果 AlCrBN涂层的物相成分为固溶的fcc-(Cr,Al)N相以及少量的CrB2和fcc-BN相。随着AlCrB靶弧电流由60 A增至100 A,表面粗糙度Sq值由197 nm增至208 nm,Sa值由107 nm增至113 nm;显微硬度由3574HK0.05先增至3890HK0.05,再降至3209HK0.05;结合强度Lc2由57 N增至63 N,再降至55 N,均呈现先增后减的趋势。不同弧电流制备的AlCrBN涂层的磨损率依次为0.69×10-15、0.38×10-15、0.84× 10-15 m3/(N?m),涂层的磨损机理均为磨粒磨损、粘着磨损和氧化磨损。切削结果显示,AlCrBN涂层刀具在切削速度VC为60 m/min和191 m/min条件下的切削寿命均高于AlCrN涂层刀具,且80 A条件下制备的AlCrBN涂层刀具切削寿命均最长,分别为9 m和6 m。切削速度60 m/min条件下的磨损机理:初期为磨粒磨损,中期为磨粒磨损和粘着磨损,后期为粘着磨损。切削速度191 m/min条件下的磨损机理:初期和中期为磨粒磨损和粘着磨损,后期为粘着磨损。结论 AlCrBN涂层刀具与AlCrN涂层刀具相比,切削性能更加优越,并且80 A条件下制备的AlCrBN涂层的综合性能最优。 相似文献
107.
目的 针对低碳钢零件的破损失效采用TIG焊电弧熔覆增材制造工艺,研究低碳钢电弧熔覆修复使其达到再制造零件性能要求的可行性,为实现TIG焊修复应用提供保证。方法 通过TIG焊熔覆在低碳钢坡口处,对熔覆接头的显微组织进行分析,并测试修复后的增材层表面硬度性能。使用Nanovea Tribometer摩擦磨损仪和NanoveaPS50表面轮廓仪,对基体和增材层进行摩擦性能测试,并表征摩擦磨损后的表面形貌,探究磨损机理。采用电化学工作站对基体和增材层的腐蚀性能进行分析。结果 修复后的增材层显微硬度(220.17HV)高于基体且其摩擦性能和腐蚀性能优于基体,随着磨损载荷的增加,增材层的摩擦系数逐渐降低,磨损机制主要为磨粒磨损和粘着磨损。增材层表面组织均匀细小,在NaCl溶液中点蚀坑小且分散,增材层的腐蚀电流密度(1.8349×10-6 A/cm2)小于基体的腐蚀电流密度(6.5251×10-5 A/cm2),增材层表面的抗腐蚀能力明显提高。结论 电弧熔覆低碳钢可满足低碳钢零部件现场电弧快速修复对再制造性能的要求,实现了低碳钢破损零部件的表面修复与强化。 相似文献
108.
《中国有色金属学会会刊》2020,30(4):1017-1030
A comprehensive study of the phase composition, microstructure evolution, microhardness and wear performance of WC-12Co composite coatings fabricated by laser cladding using coaxial powder-feed mode was presented. It was shown that a combination of high scan speed and high laser energy density made WC on the edge of WC-12Co composite powders partially melt in liquid Co and 304 stainless steel matrix, and then new carbides consisting of lamellar WC and herringbone M3W3C (M=Fe, Co) were formed. Meanwhile, WC-12Co composite coatings with no porosity, cracks and drawbacks like decarburization were obtained, showing high densification and good metallurgical bonding with the substrate. Furthermore, a considerably high microhardness of HV0.3 1500-1600, low coefficient of friction of 0.55 and wear rate of (2.15±0.31)×10-7 mm3/(N·m) were achieved owing to the synergistic effect of excellent metallurgical bonding and fine microstructures of composite coating under laser power of 1500 W. 相似文献
109.
Shaibal Roy Premkumar Kamalanathan Peter Lehner Thomas Turek Muthanna Al-Dahhan 《加拿大化工杂志》2020,98(1):294-307
Monolith reactors are widely considered as an alternative to the conventional trickle bed reactor. For the commercial deployment of monolith reactors, comparative performance studies are required. Reliable comparative and performance studies require a detailed understanding of the effect of phase distribution/maldistribution on the performance studies. In this work, performance and comparative studies were carried out in a relatively large column that was 4.8 cm in diameter. Experiments were performed in the same conditions that were used in studies for which phase distribution data were available. Since the properties of the catalyst used were different in both the reactors, the apparent kinetics were studied to facilitate the comparison. The hydrogenation of alpha-methyl styrene (AMS) was used as a test reaction. From the performance studies, it was found that the effect of maldistribution on the performance was stronger than the catalyst availability. From the comparative studies, it was found that the monolith reactor with maldistributed flow conditions provides higher productivity than the trickle bed reactor. 相似文献
110.
Yuanyuan Che Zhanglong Sun Ruirui Zhan Shuzhan Wang Shaofeng Zhou Jin Huang 《Ceramics International》2018,44(15):18067-18077
In this work, graphene oxide sheets-zirconia spheres (ZrO2-rGO) nanohybrids were fabricated by Schiff base or Michael addition reaction. Their structure was characterized by FT-IR spectroscopy, UV–vis absorption spectra, Raman spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy and atomic force microscope in detail. The reaction process of PDA-capping on rGO and APTES treatment on ZrO2 nanoparticles were verified and it was proved that the ZrO2 nanoparticles were successfully adhered onto the wrinkled surface of the graphene oxide. As a new multifunctional nanofillers, the ZrO2-rGO nanohybrids were introduced into epoxy matrix and the mechanical, thermal properties and tribological performances of the fabricated composites were also detailedly investigated. Compared with the neat EP composites, the tensile strength and elongation at break of 0.1?wt% ZrO2-rGO/EP are improved by 33% and 40%, respectively. Besides, the propagation of decomposition reactions in the composites could be impeded by anchoring ZrO2 nanoparticles on the lamellar skeleton of graphene oxide. Furthermore, the lubricating effect and strong interfacial interaction contributed by the ZrO2-rGO nanohybrids result in efficient load transfer from the matrix to the hybrids, which enables the ZrO2-rGO/EP composites to have a fairly high wear resistance performance. This novel and effective approach using ZrO2-rGO nanohybrids as multifunctional nanofillers could be beneficial to promote the development of high performance composites. 相似文献